Separation of structurally-related compounds with ionic liquids

Ionic Liquids in Separation Techniques

Recently, ionic liquids (ILs) have gained in popularity as unique solvents in different areas of separation techniques. Owing to tunable properties which can be selected by choosing appropriate cationic or anionic constituents, they can be applied in chromatographic and electro-chromatographic methods as mobile phase or stationary phase modifiers or in sample preparations processes as new extra...

Conceptual Process Design for Aromatic/Aliphatic Separation with Ionic Liquids

The investment and annual costs for a separation of aromatic hydrocarbons from a naphtha feed (~10 % aromatics) can be 35 to 70 % lower for an extraction with ionic liquids compared to an extraction with sulfolane. Aromatic hydrocarbons (benzene, toluene, ethyl benzene and xylenes) and C4 C10 aliphatic hydrocarbons are normally separated by liquid extraction, extractive distillation or azeotrop...

Interactions between Organic Compounds and Ionic Liquids. Selectivity and Capacity Characteristics of Ionic Liquids

single-step synthesis of multi-component spirobarbiturates using ionic liquids and synthesis of substituted pyridine filled with catalysts supported on solid substrate

in this thesis, a better reaction conditions for the synthesis of spirobarbiturates catalyzed by task-specific ionic liquid (2-hydroxy-n-(2-hydroxyethyl)-n,n-dimethylethanaminium formate), calcium hypochlorite ca(ocl)2 or n-bromosuccinimide (nbs) in the presence of water at room temperature by ultrasonic technique is provided. the design and synthesis of spirocycles is a challenging task becaus...

Ionic liquids showing phase separation with water prepared by mixing hydrophilic and polar amino acid ionic liquids.

Both water soluble lysine- and aspartic acid-based amino acid ionic liquids (AAILs) were mixed to prepare polar AAILs showing phase separation with water.